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辛酸咪唑啉表面活性剂的合成及性能研究
张高飞
上海发凯化工有限公司
摘要:
以正辛酸、羟乙基乙二胺和氯乙酸钠为原料,合成了辛酸咪唑啉表面活性剂,用傅里叶变换红外光谱对咪唑啉中间体进行了表征,并研究了辛酸咪唑啉物化性能。结果表明,该表面活性剂cmc为6×10- 4 mol·L-1,γcmc为29.5 mN·m-1;质量分数为0.3%时,在质量分数8%HCl溶液体系中对45#碳钢片缓蚀率为92%;发泡和稳泡能力较差,润湿性能较好。
关键词:  辛酸咪唑啉  工业清洗  低泡  缓蚀剂
DOI:10.13222/j.cnki.dc.2017.08.010
分类号:TQ423
基金项目:
Synthesis and properties of octanoic acid imidazoline surfactant
ZHANG Gao-fei
Shanghai Fine Chemical Co., Ltd.
Abstract:
Octanoic acid imidazoline surfactant was synthesized by n-octanoic acid, hydroxyethyl ethylene diamine and sodium chloroacetate. The structure of intermediate was characterized by FT-IR. The physicochemical properties of octanoic acid imidazoline were studied. The results showed that, the critical micelle concentration (cmc) was 6×10-4 mol·L-1 and the lowest surface tension (γcmc) was 29.5 mN·m-1; the corrosion inhibition efficiency to carbon steel sheets 45# in 8% hydrochloric acid solution was 91% at the concentration of 0.3%; and it exhibited poor properties of foaming and foam stability but nice wetting property.
Key words:  octanoic acid imidazoline  industrial cleaning  low-foam  corrosion inhibitor

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